html parsing with Regex

I see a couple syntactic things. The leading / and the trailing /i should be omitted. roRegEx doesn't need the / delimiters around your expression and the i (for case-insensitive), belongs in the third argument with the m. Also, you don't need to escape the forward slashes within your expression. As for the expression itself, I haven't had nearly enough caffeine yet today to even attempt.

test = CreateObject("roregex","</?\w+((\s+(\w|\w[\w-]*\w)(\s*=\s*(?:\"+chr(34)+".*?\"+chr(34)+"|"+chr(39)+".*?"+chr(39)+"|[^"+chr(39)+"\"+chr(34)+">\s]+))?)+\s*|\s*)/?>","im")

I don't know the context of what you're trying to do, but I wonder if roRegEx.Split() might be more useful. If all you want are the tags from a piece of HTML, splitting on "<" and then working on the smaller chunks might be easier.

The first rule of using a regex to parse HTML is don't do it.
The second rule of using a regex to parse HTML is PLEASE don't do it.

Below you'll find your regex in expanded form (it's a wonderful advancement in regexes, all whitespace is ignored and comments can be introduced), and commented. Maybe that will help you spot something.

I generally find it useful to reduce the regex to the bare minimum, send it against some test content, and keep adding back in stuff I think should work bit by bit until it breaks.

/
        <       # Begin tag
        \/?     # Optional slash denoting a closing element
        \w+     # Tag name
        (       # MATCH 1
                (\s+    # MATCH 2
                        \s+     # REQUIRED spaces
                        (\w|\w[\w-]*\w) # MATCH 3 (attribute), Single char or multiple chars with optional hyphen bordered by chars
                        (               # MATCH 4, OPTIONAL
                                \s*=\s* # = with optional bordering spaces
                                (?:     # Non-matching group
                                        \".*?\" # Non-greedy match of double quoted string
                                        |
                                        '.*?'   # Non-greedy match of single quoted string
                                        |
                                        [^'\">\s]+      # NOT single or double quote, right angle, or space 1+ times
                                )
                        )?
                )+
                \s*|\s*
        )
        \/?     # Optional ending slash denoting self closing element
        >
/xi